Union is the county seat for Union County
Adjacent to Union County, South Carolina
Spartanburg County (159) ►
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| On State Highway 215 at Kent Street, on the left when traveling north on State Highway 215. |
| On State Highway 215 0.1 miles east of Edwards Road, on the right when traveling east. |
| On Monument Road 1.4 miles north of Blackstock Road. |
| On Cross Keys Highway (State Highway 49) at Blackstock Road, on the left when traveling east on Cross Keys Highway. |
| On Old Buncombe Road at Jones Ford Road, on the left when traveling east on Old Buncombe Road. |
| On Old Buncombe Road, on the right when traveling west. |
| On Pea Ridge Highway (State Highway 44-13) at Mt. Joy Church Road (State Highway 44-260), on the left when traveling east on Pea Ridge Highway. |
| On Eisontown Road at Peter Hawk Creek Road on Eisontown Road. |
| On Haile Street near Webber Street, on the left when traveling south. |
| On Pea Ridge Highway (State Highway S44-13) at State Highway S44-260, on the left when traveling east on Pea Ridge Highway. |
| On Pea Ridge Highway (State Highway 44-13). |
| On Lockhart Drive at Mill Street, on the right when traveling south on Lockhart Drive. |
| On Lockhart Drive at Mill Street, on the right when traveling south on Lockhart Drive. |
| On Paula Circle, on the left. |
| Near Old Buncombe Road (State Highway S-44-18) 0.1 miles east of Galilee Church Road (State Highway S-44-63). Reported missing. |
| Near Sardis Road 0.3 miles north of Galilee CH Road, on the right when traveling north. |
| On North Mountain Street at Hames Street, in the median on North Mountain Street. |
| On Cross Keys Highway (State Highway 49) 0.5 miles west of Riley Road, on the right when traveling west. |
| On Jonesville Highway, on the right when traveling south. |
| On Cross Keys Highway (State Highway 49) at Police Club Road, on the left when traveling east on Cross Keys Highway. |
| Near Sardis Road 0.3 miles north of Galilee CH Road, on the right when traveling north. |
| On U.S. 176, on the right when traveling west. |
| On Galilee Church Road, on the left when traveling east. |
| On East Main Street, on the right when traveling east. |
| On West Main Street, on the right when traveling west. |
| On West Main Street (South Carolina Route 49) west of South Herndon Street, on the left when traveling west. |
| On Whitmire Highway (U.S. 176) north of Beatty's Bridge Road. |
| On Tinker Creek Road at Mattie Drive, on the right when traveling east on Tinker Creek Road. |
| On North Pinckney Street, on the right when traveling north. |
| On West Main Street (South Carolina Route 49) west of South Herndon Street, on the left when traveling west. |
| On Sardis Road, on the right when traveling north. |
| On Sims Drive (Highway S-44-28) at Rifle Range Road, on the left when traveling east on Sims Drive. |
| On State Highway 49 at Paula Circle, on the left when traveling west on State Highway 49. |
| On North Church Street 0.1 miles north of East Main Street (State Highway 49), on the left when traveling north. |
| On Main Street (Route 49) at Enterprise Street on Main Street. |
| On West Main Street (State Highway 49) just east of South Enterprise Street, on the right when traveling west. |
| On West Main Street at N Herndon, on the right when traveling west on West Main Street. |
| On U.S. 176, on the right when traveling south. |
| On North Enterprise Street at West Academy Street, on the right when traveling north on North Enterprise Street. |
